EDIT 06/30/10: This document described below has been superseded by a new version available in the recently published journal article “ReCal: Intercoder Reliability Calculation as a Web Service.” No changes have been made to the substance of the equations themselves, but the examples have been clarified based on referees’ suggestions.
For those of you interested in calculating intercoder reliability by hand, I have created a PDF document that contains formulae and worked examples for all of the coefficients ReCal offers. They are: percent agreement, Scott’s pi, Cohen’s kappa, Krippendorff’s alpha, and Fleiss’ kappa. If you find any errors or simply don’t understand something, please don’t hesitate to let me know either in comments or in an email.